Ivar KJELBERG
                                                                                                                                                    COMSOL Multiphysics(r) fan, retired, former "Senior Expert" at CSEM SA (CH)
                                                         
                            
                         
                                                
    
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                                                Posted:
                            
                                10 years ago                            
                            
                                2016年4月28日 GMT+8 19:20                            
                        
                        
                                                    Hi
I'm not sure I catch you fully
But yes you can define your own equations and hence dependent variables for only one or a few Entities (Domains, Boundaries ...).
You have the math mode, or different options within the physics nodes ...
But what you also can do, is to define a variable (Definition Variables) on different Entities with different expressions (one per Entity though) so that the variable represent a valid results in the different Domains/Boundaries etc
--
Good luck
Ivar                                                
                                                
                            Hi
I'm not sure I catch you fully
But yes you can define your own equations and hence dependent variables for only one or a few Entities (Domains, Boundaries ...).
You have the math mode, or different options within the physics nodes ...
But what you also can do, is to define a variable (Definition Variables) on different Entities with different expressions (one per Entity though) so that the variable represent a valid results in the different Domains/Boundaries etc
--
Good luck
Ivar                        
                                                
                                                                                                            
                                             
                        
                        
                                                
    
        Please login with a confirmed email address before reporting spam
     
    
 
                                                Posted:
                            
                                10 years ago                            
                            
                                2016年4月28日 GMT+8 19:27                            
                        
                        
                                                    Thanks for the response!
Actually I am working on modelling of vanadium crossover in vfrb. I am using Nernst- Planck eqns and secondary current distribution to model membrane and tertiary current distribution to model electrolyte on the either side of the membrane. I am facing problem in modelling the boundaries of membrane-electrolyte interface. I am considering the interfacial area of finite thickness. And the thickness is assumed to be equivalent to the diffusion boundary layer that exist at the surface of a flow-by electrode . For simplicity membrane side thickness is assumed the same.
For this, in the nernst-planck eqn, concentration and migration terms are discretized as given in the attached image file. (Screenshot001.jpg)
Fluxes for both sides of electrolyte are- (Screenshot002.jpg)
I don't know how to incorporate the boundary fluxes equations. As of now I have manually typed those equations under in Variable under local definations. But the problem is how to calculate junction concentration (c_j) . How to equate those N_er and N_mr to find out (c_j)? I am using Nernst-Planck eqn & Secondary Current Distribution to model the membrane domain and tertiary current distribution & darcy law for both electrolyte domain.
I was thinking of defining variable c_j for the membrane-electrolyte boundary that's y I asked.But I don't think it's the proper way.
I am not getting at all how to model this fluxes.
Waiting for the response.                                                
                                                
                            Thanks for the response!
Actually I am working on modelling of vanadium crossover in vfrb. I am using Nernst- Planck eqns and secondary current distribution to model membrane and tertiary current distribution to model electrolyte on the either side of the membrane. I am facing problem in modelling the boundaries of membrane-electrolyte interface. I am considering the interfacial area of finite thickness. And the thickness is assumed to be equivalent to the diffusion boundary layer that exist at the surface of a flow-by electrode . For simplicity membrane side thickness is assumed the same.
For this, in the nernst-planck eqn, concentration and migration terms are discretized as given in the attached image file. (Screenshot001.jpg)
Fluxes for both sides of electrolyte are- (Screenshot002.jpg)
I don't know how to incorporate the boundary fluxes equations. As of now I have manually typed those equations under in Variable under local definations. But the problem is how to calculate junction concentration (c_j) . How to equate those N_er and N_mr to find out (c_j)? I am using Nernst-Planck eqn & Secondary Current Distribution to model the membrane domain and tertiary current distribution & darcy law for both electrolyte domain.
I was thinking of defining variable c_j for the membrane-electrolyte boundary that's y I asked.But I don't think it's the proper way.
I am not getting at all how to model this fluxes.
Waiting for the response.