Modelling charge transfer in a slag-crucible (solid-liquid) interface

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I want to model the electronic conduction of my slag (essentially a mixture of metal oxides, containing FeO/Fe2O3 which allow for electronic conduction (i.e. electron transfer)). However in my tests I see that my platina crucible is interferring with my actual slag conduction. I want to model this test but I don't know exactly how to model the (possible) charge transfer at the slag-crucible interface. Anyone has any ideas/experience in how to model this? Thanks in advance.


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