Species adsorption in Electrocoagulation

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I am trying to simulate the electrocoagulation. And I have added the laminar flow, Secondary current distribution and also the transport of diluted species. The aluminum is getting dissolved into the solvent. and the pollutant is also getting dissolved. concentration of both species are increasing with time. I want to know 2 things. 1) How to go forward with the electrolysis at the cathode 2) How to simulate the adsorption of pollutant by another species

I want to know how to model Langmuir isotherm if possible.


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